Carbon-Sulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols
Ning Gao, Shengcai Zheng, Weikang Yang and Xiaoming Zhao*
*Department of Chemistry, Tongji University, 1239 Siping
Road, Shanghai 200092, People's Republic of China, Email: xmzhao08
mail.tongji.edu.cn
N. Gao, S. Zheng, W. Yang, X. Zhao, Org. Lett., 2011, 13, 1514-1516.
DOI: 10.1021/ol200197v
Abstract
An iridium-catalyzed regio- and enatioselective allylation of allyl carbonates with aliphatic thiols as the nucleophile in dichloromethane enables the regioselective synthesis of branched allyl sulfides in good yields and high enantioselectivity.
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Key Words
ID: J54-Y2011-0730
