Methods for the Preparation of Allenes Employing Indium- and Zinc-Mediated Dehalogenation Reactions in Aqueous Solutions
Mei-Huey Lin*, Wen-Shing Tsai, Long-Zhi Lin, Shiang-Fu Hung, Tsung-Hsun Chuang and Yi-Jen Su
*Department of Chemistry, National Changhua University of
Education, Changhua, Taiwan 50007,
Email: mhlin
cc.ncue.edu.tw
M.-H. Lin, W.-S. Tsai, L.-Z. Lin, S.-F. Hung, T.-H. Chuang, Y.-J. Su, J. Org. Chem., 2011, 76, 8518-8523.
DOI: 10.1021/jo2015104
Abstract
Simple and mild indium- and zinc-mediated dehalogenation reactions of vicinal dihalides in an aqueous solvent enable the synthesis of various allenylmethyl aryl ethers and monosubstituted allenes in very good yields.
see article for more examples
Key Words
ID: J42-Y2011-3100
