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Direct Catalytic Azidation of Allylic Alcohols

Magnus Rueping*, Carlos Vila and Uxue Uria

*Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany, Email: magnus.ruepingrwth-aachen.de

M. Rueping, C. Vila, U. Uria, Org. Lett., 2012, 14, 768-771.

DOI: 10.1021/ol203310h



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Abstract

A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols affords the corresponding allylic azides in high to excellent yields and regioselectivities. The reaction provides straightforward access to allylic azides that are valuable intermediates in organic synthesis.

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Key Words

allyl azides


ID: J54-Y2012-0260