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Electrochemical Deoxygenation of Primary Alcohols

Kevin Lam, István E. Markó*

*Département de Chimie, Bâtiment Lavoisier, Université catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium, Email: istvan.markouclouvain.be

K. Lam, I. E. Markő, Synlett, 2012, 23, 1235-1239.

DOI: 10.1055/s-0031-1290778 (free Supporting Information)


Abstract

Direct electrolysis of primary alcohols  leads smoothly to the formation of the corresponding deoxygenated product in high yield in the presence of methyl toluate.

see article for more examples



Organic electrosynthesis using toluates as simple and versatile radical precursors

K. Lam, I. E. Markó, Chem. Commun., 2009, 95-97.


Key Words

deoxygenation, electrochemical, esters, reduction, free radicals, electrochemistry


ID: J60-Y2012-1460