Copper-Catalyzed Amination of Silyl Ketene Acetals with N-Chloroamines
Tomoya Miura*, Masao Morimoto and Masahiro Murakami*
*Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan, Email: tmiurasbchem.kyoto-u.ac.jp, murakamisbchem.kyoto-u.ac.jp
T. Miura, M. Morimoto, M. Murakami, Org. Lett., 2012, 14, 5214-5217.
DOI: 10.1021/ol302331k
Abstract
A copper(I)/2,2′-bipyridyl complex catalyzes an amination reaction of silyl ketene acetals with N-chloroamines to give α-amino esters in good yield.
see article for more examples
Key Words
ID: J54-Y2012-3290