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Synthesis of Biaryl Derivatives via a Magnetic Pd-NPs-Catalyzed One-Pot Diazotization-Cross-Coupling Reaction

Yan Zong, Jiefeng Hu, Peipei Sun*, Xiaoqing Jiang*

*College of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210097, P. R. of China, Email: jiangxiaoqingnjnu.edu.cn, sunpeipeinjnu.edu.cn

Y. Zong, J. Hu, P. Sun, X. Jiang, Synlett, 2012, 23, 2393-2396.

DOI: 10.1055/s-0032-1317097 (free Supporting Information)


Abstract

Magnetic Pd-Nanoparticles catalyzes a one-pot diazotization-cross-coupling reaction of anilines and arylboronic acids to yield biaryls in good to excellent yields. The catalyst can recovered through magnetic separation and reused for three times. There were several obvious advantages such as broad applicability, high selectivity, simply experimental operation as well as the convenient preparation, high efficiency and reusability of catalyst.

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Key Words

nanopalladium, catalysis, diazotization, Suzuki coupling, magnetic separation, biaryls


ID: J60-Y2012-3310