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A Simple and Efficient Method for One-Pot, Three-Component Synthesis of Terminal Vinylphosphonates Using a Task-Specific Ionic Liquid

Sara Sobhani*, Moones Honarmand

*Department of Chemistry, College of Sciences, University of Birjand, Birjand 414, Iran, Email: ssobhanibirjand.ac.ir

S. Sobhani, M. Honarmand, Synlett, 2013, 24, 236-240.

DOI: 10.1055/s-0032-1317965 (free Supporting Information)


Abstract

A convenient and practical method for the one-pot, three-component synthesis of terminal vinylphosphonates from aldehydes, nitromethane and trialkylphosphites through a tandem Henry-Michael reaction followed by nitro elimination in the presence of 5-hydroxypentylammonium acetate (5-HPAA) as a task-specific ionic liquid offers good yields of the products under mild reaction conditions.

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Key Words

phosphonates, multicomponent reactions, phosphite esters, ionic liquids, aldehydes


ID: J60-Y2013-0220