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Cross-Coupling of ArX with ArMgBr Catalyzed by N-Heterocyclic Carbene-Based Nickel Complexes

Wang-Jun Guo and Zhong-Xia Wang*

*CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People’s Republic of China, Email: zxwangustc.edu.cn

W.-J. Guo, Z.-X. Wang, J. Org. Chem., 2013, 78, 1054-1061.

DOI: 10.1021/jo302425x (free Supporting Information)


Abstract

N-Heterocyclic carbene-based pincer nickel complexes efficiently catalyze cross-coupling of aryl Grignard reagents with aryl chlorides or fluorides under mild conditions.

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Amido Pincer Nickel Catalyzed Kumada Cross-Coupling of Aryl, Heteroaryl, and Vinyl Chlorides

X.-Q. Zhang, Z.-X. Wang, Synlett, 2013, 24, 2081-2084.

Kumada Coupling of Aryl, Heteroaryl, and Vinyl Chlorides Catalyzed by Amido Pincer Nickel Complexes

N. Liu, Z.-X. Wang, J. Org. Chem., 2011, 76, 10031-10032.


Key Words

Kumada Coupling, Biaryls


ID: J42-Y2013-0270