Oxidative Diamination Promoted by Dinuclear Iodine(III) Reagents
Caren Röben, José A. Souto, Eduardo C. Escudero-Adán and Kilian Muńiz*
*ICIQ - Institute of Chemical Research of Catalonia, Av. Paďsos Catalans 16, 43007 Tarragona, Spain, Email: kmuniziciq.es
C. Röben, J. A. Souto, E. C. Escudero-Adán, K. Muńiz, Org. Lett., 2013, 15, 1008-1011.
DOI: 10.1021/ol3034884
see article for more reactions
Abstract
Dinuclear iodine(III) reagents with a defined structure enable an intermolecular diamination of alkenes. These highly reactive hypervalent iodine(III) compounds are accessible through protolytic aminolysis events, which generate defined imido-iodine(III) groups.
see article for more examples
Key Words
Diamination, Iodine(III) reagents
ID: J54-Y2013-0530