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Amido Pincer Nickel Catalyzed Kumada Cross-Coupling of Aryl, Heteroaryl, and Vinyl Chlorides

Xue-Qi Zhang, Zhong-Xia Wang*

*Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People’s Republic of China, Email: zxwangustc.edu.cn

X.-Q. Zhang, Z.-X. Wang, Synlett, 2013, 24, 2081-2084.

DOI: 10.1055/s-0033-1339653 (free Supporting Information)


Abstract

Amido pincer nickel complexes efficiently catalyze the cross-coupling of activated, unactivated, and deactivated aryl chlorides, N-heteroaryl chlorides, 1,4-dichlorobenzene, and vinyl chlorides with aryl Grignard reagents.

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Key Words

nickel, cross-coupling, Kumada Coupling, aryl Grignard reagents, aryl chlorides, vinyl chlorides


ID: J60-Y2013