Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium
Zachary D. Miller, Wei Li, Tomás R. Belderrain and John Montgomery*
*Department of Chemistry, University of Michigan, 930 North
University Avenue, Ann Arbor, Michigan 48109-1055, United States, Email:
jmontg
umich.edu
Z. D. Miller, W. Li, T. R. Belderrain, J. Montgomery, J. Am. Chem. Soc., 2013, 135, 15282-15285.
DOI: 10.1021/ja407749w
Abstract
In regioselective methods for allene hydrosilylation, alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene (NHC) ligands, whereas allylsilanes are produced via palladium catalysis with smaller NHC ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol.
see article for more examples
Regioselective Allene Hydroarylation via One-Pot Allene Hydrosilylation/Pd-Catalyzed Cross-Coupling
Z. D. Miller, J. Montgomery, Org. Lett., 2014, 16, 5486-5489.
Key Words
ID: J48-Y2013
