Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds
Tao Wang, Shuai Sang, Liu Liu, Hongwei Qiao, Yuxing Gao* and Yufen Zhao
*College of Chemistry and Chemical Engineering, Xiamen
University, Xiamen 361005, Fujian, China, Email: gaoxingchem
xmu.edu.cn
T. Wang, S. Sang, L. Liu, H. Qiao, Y. Gao, Y. Zhao, J. Org. Chem., 2014, 79, 608-617.
DOI: 10.1021/jo402392t
Abstract
A novel and highly efficient Pd-catalyzed cross-coupling of triarylbismuths with various P(O)-H compounds proceeds smoothly without exclusion of moisture or air and provides valuable arylphosphonates, arylphosphinates, and arylphosphine oxides, with high atom-economy, operational simplicity of the procedure, and good to high yield.
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Key Words
phosphonates, phosphinates, phosphine oxides
ID: J42-Y2014
