Rh(I)-Catalyzed Cross-Coupling of α-Diazoesters with Arylsiloxanes
Ying Xia, Zhen Liu, Sheng Feng, Fei Ye, Yan Zhang and Jianbo Wang*
*Key Laboratory of Bioorganic Chemistry and Molecular
Engineering of Ministry of Education, College of Chemistry, Peking University,
Beijing 100871, China, Email: wangjb
pku.edu.cn
Y. Xia, Z. Liu, S. Feng, F. Ye, Y. Zhang, J. Wang, Org. Lett., 2015, 17, 956-959.
DOI: 10.1021/acs.orglett.5b00052
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Abstract
A Rh(I)-catalyzed cross-coupling of diazoesters with arylsiloxanes enables the synthesis of α-aryl esters via Rh(I)-carbene migratory insertion. The reaction represents the first example of utilizing arylsiloxane as the coupling partner in a carbene-involved cross-coupling reaction.
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Key Words
ID: J54-Y2015
