Pd/C Catalyzed Carbonylation of Azides in the Presence of Amines
Jin Zhao, Zongyang Li, Shuaihu Yan, Shiyang Xu, Ming-An Wang, Bin Fu and Zhenhua Zhang*
*Department of Applied Chemistry, China Agricultural University, Beijing 100193, China, Email: zhangzhhcau.edu.cn
J. Zhao, Z. Li, S. Yan, S. Xu, M.-A. Wang, B. Fu, Z. Zhang, Org. Lett., 2016, 18, 1736-1739.
DOI: 10.1021/acs.orglett.6b00381
see article for more reactions
Abstract
A facile and efficient Pd/C-catalyzed carbonylation of both aliphatic and aromatic azides in the presence of amines under CO atmosphere provides functionalized unsymmetrical ureas with N2 as the only byproduct.
see article for more examples
Key Words
ID: J54-Y2016