Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes
Ivan Buslov, Sébastien Carlos Keller and Xile Hu*
*Laboratory of Inorganic Synthesis and Catalysis, Institute
of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL),
ISIC-LSCI, BCH 3305, Lausanne 1015, Switzerland, Email: xile.hu
epfl.ch
I. Buslov, S. C. Keller, X. Hu, Org. Lett., 2016, 18, 1928-1931.
DOI: 10.1021/acs.orglett.6b00792
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Abstract
Gaseous and flammable silanes are inconvenient to use in chemical reactions. Catalytic amounts of a nickel pincer complex and NaOtBu enable the synthesis of alkyl hydrosilanes from alkenes and alkoxy hydrosilanes. The scope and mechanism of the hydrosilylation reactions are also described.
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Key Words
ID: J54-Y2016
