Gold-Catalyzed Anti-Markovnikov Selective Hydrothiolation of Unactivated Alkenes
Taichi Tamai, Keiko Fujiwara, Shinya Higashimae, Akihiro Nomoto and Akiya Ogawa*
*Department of Applied Chemistry, Graduate School of
Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka
599-8531, Japan, Email: ogawa
chem.osakafu-u.ac.jp
T. Tamai, K. Fujiwara, S. Higashimae, A. Nomoto, A. Ogawa, Org. Lett., 2016, 18, 2114-2117.
DOI: 10.1021/acs.orglett.6b00746
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Abstract
A gold-catalyzed hydrothiolation of unactivated alkenes proceeds effectively to give anti-Markovnikov-selective adducts in good yields and in a regioselective manner.
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proposed mechanism
Key Words
ID: J54-Y2016
