Silicon-Carbon Bond Formation via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl Electrophiles
Crystal K. Chu, Yufan Liang and Gregory C. Fu*
*Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States, Email: gcfucaltech.edu
C. K. Chu, Y. Liang, G. C. Fu, J. Am. Chem. Soc., 2016, 138, 6404-6407.
DOI: 10.1021/jacs.6b03465
see article for more reactions
Abstract
A simple, commercially available nickel catalyst (NiBr2·diglyme) can achieve couplings of unactivated alkyl bromides with nucleophilic silicon reagents under unusually mild conditions.
see article for more examples
Key Words
ID: J48-Y2016