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Ligandless Palladium-Catalyzed Reductive Carbonylation of Aryl Iodides under Ambient Conditions

Wei Han*, Binbin Liu, Junjie Chen, Qing Zhou

*Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road NO.1, Nanjing 210023, P. R. of China, Email: hanweinjnu.edu.cn

W. Han, B. Liu, J. Chen, Q. Zhou, Synlett, 2017, 28, 835-840.

DOI: 10.1055/s-0036-1588930 (free Supporting Information)


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Abstract

A ligandless palladium-catalyzed reductive carbonylation of aryl iodides for the synthesis of aromatic aldehydes proceeded effectively even under ambient temperature and pressure.

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Key Words

aromatic aldehydes, aryl iodides, reductive carbonylation, formylation, ligandless, ambient conditions, triethylsilane


ID: J60-Y2017