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The First Asymmetric Intramolecular Stetter Reaction

Dieter Enders*, Klaus Breuer and Jan Runsink

*Institut für Organische Chemie der Technischen Hochschule, Landoltweg 1, D-52074 Aachen, Email: endersrwth.aachen.de

D. Enders, K. Breuer, J. Runsink, Helv. Chim. Acta, 1996, 79, 1899-1902.


Abstract

The first enantioselective intramolecular catalytic Stetter reaction, which opens up a short and efficient pathway to enantiomerically enriched chroman-4-ones, is reported.

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model explaining the facial selectivity



Key Words

Stetter 1,4-Dicarbonyl Synthesis, Organocatalysis, Chromanones


ID: J30-Y1996-020