Cobalt(I)-catalyzed 1,4-Hydrovinylation Reactions of 1,3-Dienes with Functionalized Terminal Alkenes under Mild Conditions
Gerhard Hilt*, Steffen Lüers
*Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße,
35043 Marburg, Germany, Email: hilt
chemie.uni-marburg.de
G. Hilt, S. Lüers, Synthesis, 2002, 609-618.
DOI: 10.1055/s-2002-23549
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Abstract
A mild, cobalt-catalyzed 1,4-hydrovinylation of acyclic 1,3-dienes with various functionalized terminal alkenes is described. Unsymmetrical 1,3-dienes yield products, where the new carbon-carbon bond is formed at the less substituted end of the 1,3-diene.
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Cobalt-catalysed Diels-Alder, 1,4-Hydrovinylation and 1,4-Hydrosilylation Reactions of Non-Activated Starting Materials on a Large Scale
G. Hilt, S. Lüers, F. Schmidt, Synthesis, 2004, 634-638
DOI: 10.1055/s-2003-44373
Key Words
Cobalt, 1,4-Hydrovinylation Reactions, Alkenes, 1,3-Diene, 1,4-Dienes
ID: J66-Y2002-1480
