Bidentate Ligands by Self-Assembly through Hydrogen Bonding: A General Room Temperature/Ambient Pressure Regioselective Hydroformylation of Terminal Alkenes
Wolfgang Seiche, Alexander Schuschkowski, Bernhard Breit*
*Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität
Freiburg, Albertstr. 21, 79104 Freiburg, Germany, Email: bernhard.breit
orgmail.chemie.uni-freiburg.de
W. Seiche, A. Schuschkowski, B. Breit, Adv. Syn. Catal., 2005, 1488-1494.
DOI: 10.1002/adsc.200505174
Abstract
The 6-DPPon/rhodium catalyst allows for the first time a room temperature/ambient pressure hydroformylation of various, structurally diverse terminal alkenes with low catalyst loadings. This protocol omits the need for special pressure equipment and should find wide application in organic synthesis.
Key Words
Hydroformylation, Carbonyl Compounds
ID: JXX-Y2005-2760
