Broadly Effective Enantioselective Diels-Alder Reactions of 1-Amino-substituted-1,3-butadienes
Young Huang, Tetsuo Iwama and Viresh H. Rawal*
*Department of Chemistry, The University of Chicago, 5735 South Ellis
Avenue, Chicago, Illinois 60637, Email: vrawal
uchicago.edu
Y. Huang, T. Iwama, V. H. Rawal, Org. Lett., 2002, 4, 1163-1166.
DOI: 10.1021/ol0255716 (free Supporting Information)
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Abstract
Methacrolein underwent enantioselective Diels-Alder reactions with a broad range of 1-amino-1,3-butadiene derivatives in the presence of a Cr(III)-salen catalyst. High yields and excellent enantioselectivity were achieved at room temperature.
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Key Words
ID: J54-Y2002-610
