Pauson-Khand reactions catalyzed by entrapped rhodium complexes
Kuang Hyun Park, Seung Uk Song and Young Keun Chung*
*School of Chemistry for Molecular Catalysis, Seoul National University,
Seoul 151-747, South Korea, Email: ykchung
plaza.snu.ac.kr
K. H. Park, S. U. Song, Y. K. Chung, Tetrahedron Lett., 2003, 44, 2827-2830.
DOI: 10.1016/S0040-4039(03)00434-9
Abstract
An entrapped Rh catalyst derived by a sol-gel process has been used in a Pauson-Khand reaction under mild conditions. The catalyst can be reused at least 10 times without losing activity. This catalytic system is not effective for intermolecular reactions.
see article for more examples
Key Words
Pauson-Khand Reaction, Pauson-Khand Cyclopentenone Annulation, Cyclopentenones, Enones
ID: J72-Y2003-060
