First Heck Reaction with Arenediazonium Cations with Recovery of Pd-Triolefinic Macrocyclic Catalyst
Judit Masllorens, Marcial Moreno-Maņas, Anna Pla-Quintana and Anna Roglans*
Department of Chemistry, Universitat de Girona, Girona, 17071-Girona, Spain,
Email: anna.roglans
udg.es
J. Masllorens, M. Moreno-Maņas, A. Pla-Quintana, A. Roglans, Org. Lett., 2003, 5, 1559-1561.
DOI: 10.1021/ol034340b (free Supporting Information)
Abstract
An air- and moisture-stable, recoverable phosphine-free triolefinic macrocyclic palladium(0) complex is highly active for Heck olefination of aryl diazonium tetrafluoroborates. The reactions can be performed under air at room temperature to give the coupled products in high yields.
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Key Words
Heck Reaction, Heck Matsuda Reaction
ID: J54-Y2003-430
