An Air and Thermally Stable One-Component Catalyst for the Amination of Aryl Chlorides
Danilo Zim and Stephen L. Buchwald*
*Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, Email: sbuchwalmit.edu
D. Zim, S. L. Buchwald, Org. Lett., 2003, 5, 2413-2415.
DOI: 10.1021/ol034561h (free Supporting Information)
A new, highly efficient palladacyclic precatalyst is air, moisture, and thermally stable and enables the amination of aryl chlorides without many of the limitations of methods previously described.
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