Bulky Trialkylsilyl Acetylenes in the Cadiot-Chodkiewicz Cross-Coupling Reaction
Joseph P. Marino* and Hanh Nho Nguyen
*Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109,
Email: jmarino
nd.edu
J. P. Marino, H. N. Nguyen, J. Org. Chem., 2002, 67, 6841-6844.
DOI: 10.1021/jo025745x (free Supporting Information)
Abstract
Bulky trialkylsilyl-protected alkynes were coupled with different bromoalkynes to form a variety of synthetically useful unsymmetrical diynes in good yields.
Zusammenfassung
Sterisch gehinderte Trialkylsilyl-geschützte Alkine konnten erfolgreich mit unterschiedlichen Bromoalkinen gekuppelt werden. Es wurden nützliche, unsymmetrische Diin-Bausteine in guten Ausbeuten erhalten.
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Key Words
Schlüsselworte
Cadiot-Chodkiewicz-Kupplung
ID: J42-Y2002-840
