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Highly Active Catalyst for the Heterogeneous Suzuki-Miyaura Reaction: Assembled Complex of Palladium and Non-Cross-Linked Amphiphilic Polymer

Yoichi M. A. Yamada, Koji Takeda, Hideyo Takahashi and Shiro Ikegami*

*Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan, Email: shi-ikepharm.teikyo-u.ac.jp

Y. M. A. Yamada, K. Takeda, H. Takashashi, S. Ikegami, J. Org. Chem., 2003, 68, 7733-7741.

DOI: 10.1021/jo034354v (free Supporting Information)


Abstract

An insoluble, amphiphilic and polymeric palladium catalyst (PdAS) is an excellent catalyst for the Suzuki-Miyaura reaction. The catalyst is reusable after easy work up and showed good stability in any reaction medium.


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Key Words

Suzuki-Miyaura Coupling, Biaryls, Styrenes, Arenes (alkylation), Alkenes, Benzylation


ID: J42-Y2003-990