The facile preparation of alkenyl metathesis synthons
Travis W. Baughman, John C. Sworen and Kenneth B. Wagener
*The George and Josephine Butler Polymer Research Laboratory, Department of
Chemistry, University of Florida, PO Box 117200, Gainesville, FL 32605, USA,
Email: wagener
chem.ufl.edu
T. W. Baughman, J. C. Sworen, K. B. Wagener, Tetrahedron, 2004, 60, 10943-10948.
DOI: 10.1016/j.tet.2004.09.021
Abstract
The preparation of alkenyl halides of any length from inexpensive starting reagents is reported. Standard organic transformations were used to prepare straight-chain α-olefin halides in excellent overall yields with no detectable olefin isomerization and full recovery of any unreacted starting material.
see article for more reactions
Zusammenfassung
Die Synthese von unterschiedlich langen Alkenylhalogeniden aus günstigen Ausgangsverbindungen wird beschrieben. Gebräuchliche Methoden ermöglichen die Herstellung gerad-kettiger α-Olefine in sehr guten Ausbeuten und ohne Olefin-Isomerisierung.
Key Words
Appel Reaction, Finkelstein Reaction, Cross-metathesis, α-Olefins, Alkenyl halides, ADMET, Metathesis
Schlüsselworte
Appel-Reaktion, Finkelstein-Reaktion, Kreuzmetathese, α-Olefine, Alkenylhalogenide, ADMET, Metathese
ID: J72-Y2004-1010
