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Clean and Highly Selective Oxidation of Alcohols in an Ionic Liquid by Using an Ion-Supported Hypervalent Iodine(III) Reagent

Weixing Qian, Erlei Jin, Weiliang Bao, Yongmin Zhang*

*Department of Chemistry, Zhejiang University, Xi Xi Campus, Hangzhou, Zhejiang 310028, P. R. China , Email:

W. Qian, E. Jin, W. Bao, Y. Zhang, Angew. Chem. Int. Ed., 2005, 44, 952-955.

DOI: 10.1002/anie.200461889 (free Supporting Information)


[dibmim][BF4] can be used for the oxidation of alcohols to carbonyl compounds. This oxidizing agent offers a high degree of selectivity for the oxidation of primary alcohols to carbonyl compounds without oxidation to carboxylic acids in ionic liquids. [dibmim][BF4] can be reused after oxidation with peracetic acid.

see article for more examples

Efficient and Highly Selective Oxidation of Sulfides to Sulfoxides in the Presence of an Ionic Liquid Containing Hypervalent Iodine

W. Qian, L. Pei, Synlett, 2006, 709-712.

Key Words

alcohols, aldehydes, ketones, hypervalent iodine compounds, iodine, ionic liquids, oxidation

ID: J54-Y2005-120