Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters
Tatsuo Ishiyama, Miki Murata and Norio Miyaura*
*Research Group of Synthetic Organic Chemistry, Graduate School of Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo 060-8628, Japan, Email: miyauraorg-mc.eng.hokudai.ac.jp
T. Ishiyama, M. Murata, N. Miyaura, J. Org. Chem., 1995, 60, 7508-7510.
A palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with haloarenes enables a direct synthesis of arylboronic esters. The role of the acetate ion is discussed.
see article for more examples