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1,1,1-Trifluoroacetone

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1,1,1-Trifluoroacetone can be used as a hydride-acceptor in the Oppenauer oxidation of secondary alcohols in the presence of diethylethoxyaluminum. The oxidant enables a selective oxidation of secondary alcohols in the presence of primary alcohols.
R. Mello, J. Martínze-Ferrer, G. Asensio, M. E. González-Núñez, J. Org. Chem., 2007, 72, 9376-9378.