Tetramethyldisiloxane (TMDSO, TMDS)
Recent Literature
TMDS is an efficient hydride source for the reduction of tertiary and secondary
phosphine oxides using a catalytic amount of Ti(OiPr)4. All
classes of tertiary phosphine oxides, such as triaryl, trialkyl, and diphosphine
were effectively reduced.
M. Berthod, A. Favre-Réguillon, J. Mohamad, G. Mignani, G. Docherty, M. Lemaire, Synlett, 2007,
1545-1548.
A highly Marknovikov selectiv conversion of various olefins to azides
was achieved using a cobalt catalyst, 3 equiv of TsN3 as
nitrogen source and simple silanes (PhSiH3, TMDSO).
J. Waser, H. Nambu, E. M. Carreira, J. Am. Chem. Soc., 2005,
127, 8294-8295.
