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Search results for: brook rearrangement
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... . A. G. Brook, Acc. Chem ... brook-a-g.shtm ... : ORGANOMETALLICS/SILICON/REARRANGEMENT/C=C-M ...
... Key Words Corey-Seebach Reaction, Brook Rearrangement, ?-Hydroxy Ketones ... a solvent controlled 1,4-Brook rearrangement leading to a ... distal anion, which reacts with various electrophiles. see ...
... Key Words Benzoin Condensation, Brook Rearrangement, ?-hydroxy carbonyls ... ketones, phase-transfer catalysis, rearrangements, umpolung ID: ... ketones, phase-transfer catalysis, rearrangements, umpolung ID: ...
... Strategy for Construction of Eight-Membered Carbocycles by Brook Rearrangement Mediated [6+ 2 Annulation ... Takeda,* Hidekazu Haraguchi and Yasushi Okamoto *Department of Synthetic Organic Chemistry, ...
... to acylsilanes and a subsequent 1,2-Brook rearrangement generate ?-silyloxy homoenolates nucleophiles that undergo ... addition to alkyl halides, aldehydes, and ketones. see article for more examples ...
... , silyl rearrangement, silyl ethers, Brook rearrangement ID: J66-Y2004-2440 ... allylic alcohols, copper alkoxides, silyl rearrangement, silyl ethers, Brook rearrangement ID ...
... , Ketones, Arylketones, Enones, Brook Rearrangement ID: J48-Y2006-3590 ... Stereoselective Preparation of 1-Siloxy-1-alkenylcopper Species by 1,2-Csp2-to-O Silyl Migration of Acylsilanes ...
... corresponding propargylsilanes in a base-catalyzed 1,2-Brook rearrangement/S E 2' process ... Conversion to the silyloxyallenes occurs with minimal erosion in optical activity. see article for ...
... , 128, 15382-15383. Key Words Brook Rearrangement, Baylis-Hillman Adducts ID: J54-Y2007-2030 ... N-Heterocyclic Carbene-Initiated ?-Acylvinyl Anion Reactivity: Additions of ?-Hydroxypropargylsilanes to Aldehydes ...
... ). Iwao Ojima of SUNY Stony Brook focused (Org. Lett. 2006 ... On deprotonation followed by silylation, Ireland-Claisen rearrangement proceeded with high diastereocontrol. The product ...
