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Search results for: cope elimination
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... a New Variant of the Cope Elimination Roger J. ... functions. These undergo a Cope-type elimination to a vinylsulfone ... can be captured by amines to afford ?-aminoethylsulfones. The ...
... of complex cyclic ketones by oxy-Cope rearrangement. L. ... INTERMEDIATE/HELICAL EQUILIBRATION/COPE REARRANGEMENT/SYNTHETIC UTILITY ... ; field effects; intramolecular eliminations; electrophilic radicals; ...
... gave 15, poised for aza-Cope rearrangement to 2. ... based on the aza- Cope /intramolecular Mannich reorganization ... cyclized without epimerization. A preliminary study with material resolved ...
... Reactions in 3-Aryl 2,3-Dihalopropanoates: Scope and Mechanistic Insights Wei Li,* ... Organic Chemistry Portal Dimethyl Sulfoxide Mediated Elimination Reactions in 3-Aryl 2,3-Dihalopropanoates: ...
... ethers from aryl halides and triflates: Scope and mechanism. J. F. ... complex/palladium/coupling/reductive elimination/CROSS-COUPLING REACTIONS/OXYGEN-ATOM TRANSFER/ ...
... ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a ... Halogen Acceleration Effect Nicolas Gernigon, Raed M. Al-Zoubi and Dennis G. Hall ...
... . see article for more examples Substrate Scope and Selectivity Using Unsymmetrical Alkyl Halides and ... Cobalt Catalysis to Override E2-Selectivity in the Elimination of Alkyl Halides: A Mild Route ...
... high efficiency, and a wide substrate scope. see article for more examples proposed ... 4+ 1] Cycloaddition/E1cb Elimination/Aromatization Sequence of Sulfur Ylides and ...
... NaHMDS or NaOtBu. To enlarge the scope of this process to include base-sensitive groups ... . These hindered ligands both accelerate reductive elimination and promote oxidative addition. The use ...
... indole, additives, mechanism and the scope of the reaction. Figure 1 - ... enantioselective FC alkylation of indole. In preliminary tests (Scheme 1), the ...