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... -geometry. While formation of the Hofmann products is generally favored, selectivity toward ... examples proposed mechanism Key Words cyclohexenes , eliminations , Hofmann rule ID: J54-Y2019 ...
... /NH2/AMINES/BECKMANN/HOFMANN/CURTIUS/SCHMIDT/LOSSEN/ ... C-X/HA/HALIDES/REARRANGEMENT ELIMINATION S. Patai, in The Chemistry ...
... the highly congested tertiary amine 16 underwent Hofmann-like elimination to the corresonding secondary amine 17 ... only slightly elevated temperature (J . Org. Chem. 2020, 85, ...
... JACS , and is related to the Hofmann-Loffler-Freytag reaction (1 ,3-bromination via atom ... , 11-epieudesmantetraol and eudesmantetraol, by firstly eliminating the bromide with tetramethylpiperidine, and then ...