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... preparation of 2 began with the enantioselective Robinson annulation of the ?-keto ester 4 with ... (5), mediated by the organocatalyst 6. In this protocol, originally ...
... Organic Chemistry Portal The Robinson Annelation and Related Reactions. R. E. ... Key Words: C-C BOND FORMATION/ANNULATIONS/6-RING/ROBINSON ANNELATION The Beckmann ...
... ketone 30 can be converted into the Robinson annulation product 32 without epimerization at the ... position. This led to 33, cycloaddition of which with 34 delivered (- ...
