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Search results for: baeyer-villiger oxidation

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... to use a rather convoluted reduction/oxidation approach over four steps to achieve what ... group a methyl ketone. A subsequent Baeyer-Villiger oxidation formed an ester such that the ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn06/englerin-a-nicolaou-chen.shtm
... expected diaxial product 9, which on oxidation gave 10 in high enantiomeric excess. ... of hydrogen peroxide, the ketone underwent Baeyer-Villiger oxidation with high regioselectivity. The silane ...
URL: http://www.organic-chemistry.org/Highlights/2006/01May.shtm
... hydrolysis, the cyclobutanone 5. Baeyer-Villiger oxidation of 5 led to 5-Deoxystrigol (6 ... after hydrolysis, the cyclobutanone 5. Baeyer-Villiger oxidation of 5 led to 5-Deoxystrigol ( ...
URL: http://www.organic-chemistry.org/Highlights/2015/31August.shtm
... expanded to a ?-lactone using a Baeyer-Villiger oxidation. All in a very high yield ... the expanded to a ?-lactone using a Baeyer-Villiger oxidation. All in a very high ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn05/tricholomalide-a-b-danishefsky.shtm
... , to give, after selenation and oxidation, the dienenone 16. The acetoxy ... to the diene 10, followed by Baeyer-Villiger cleavage to give 13. This established ...
URL: http://www.organic-chemistry.org/Highlights/2007/05March.shtm
... ACETATE/AFLATOXIN B-1 BIOSYNTHESIS/BAEYER-VILLIGER OXIDATION Type I polyketide biosynthesis in bacteria ( ... HEMIACETAL ACETATE/AFLATOXIN B-1 BIOSYNTHESIS/BAEYER-VILLIGER OXIDATION Type I polyketide biosynthesis in bacteria ...
URL: http://www.organic-chemistry.org/abstracts/authors/rawlings-b-j.shtm
... , 5506.) 31 by Shi epoxidation. Although several competing reduction products were ... 50, 8387.) an over-expressed Baeyer-Villiger monoxygenase to prepare 6 by dynamic kinetic ...
URL: http://www.organic-chemistry.org/Highlights/2012/16July.shtm
... a rare example of an enantioselective Baeyer-Villiger oxidation of 4-alkyl cyclohexanones, such as 14 ... ) a rare example of an enantioselective Baeyer-Villiger oxidation of 4-alkyl cyclohexanones, such as ...
URL: http://www.organic-chemistry.org/Highlights/2013/08April.shtm
... Key Words: GLYCOSIDASE-CATALYZED SYNTHESIS/BAEYER-VILLIGER OXIDATIONS/EFFICIENT CHEMOENZYMATIC SYNTHESIS/DYNAMIC KINETIC ... . Key Words: GLYCOSIDASE-CATALYZED SYNTHESIS/BAEYER-VILLIGER OXIDATIONS/EFFICIENT CHEMOENZYMATIC SYNTHESIS/DYNAMIC ...
URL: http://www.organic-chemistry.org/abstracts/authors/davies-b-g.shtm
... able to carry out the enantioselective Baeyer-Villiger oxidation of 10 on a multi-gram scale. ... was able to carry out the enantioselective Baeyer-Villiger oxidation of 10 on a multi-gram scale ...
URL: http://www.organic-chemistry.org/Highlights/2007/09April.shtm
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