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Search results for: cope rearrangement
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... ketone 4, to give 7. Oxy-Cope rearrangement then gave the 5-9-5 enolate, ... was quenched with methyl iodide to give 8. The ketone 8 underwent spontaneous intramolecular ...
... et al. from Glaxo-Smith-Kline investigated in-depth scope and limitations of this imidazole synthesis ( ... bond, a base-induced cyclisation and proton rearrangement towards an imidazoline, which upon loss ...
... protected amine 7. This underwent smooth aza-oxy-Cope rearrangement, to give, after protection ... bromination, the ketone 1. The acid-mediated cyclization of 1 to 2 proceeds by ...
... Cyclopropenone Ketals, and Related Systems: Scope and Applications. D. L. ... AGENT/INHIBITORS PDE-I/BENZYLIC HYDROPEROXIDE REARRANGEMENT/ENHANCED FUNCTIONAL ANALOGS/MINOR-GROOVE BINDING ...
... by Kobayashi. Sequential imine formation, aza-Cope rearrangement, and hydrolysis led to 1 ... 94% de. One could envision reduction of the lactam carbonyl of 1 to ...
... STEREOCONTROLLED TOTAL SYNTHESIS/CHROMIUM-REFORMATSKY REACTION/SILYLOXY-COPE REARRANGEMENT/EFFICIENT TOTAL SYNTHESIS/LOW-VALENT ... /NEOCARZINOSTATIN CHROMOPHORE ANALOGS/ENANTIOSELECTIVE TOTAL SYNTHESIS/CONTAINING NATURAL-PRODUCTS Venturing into catalysis based ...
... the enantiomercially-pure 7 on, by Pd-catalyzed Cope rearrangement, to 8 and so to ... -)-Kainic Acid (9). M .-Lluïsa Bennasar of the University of Barcelona ...
