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Search results for: curtius rearrangement

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... of the methoxycarbonyl moiety, such as Curtius rearrangement, hydrolysis to carboxylic acid, ... the conversion into amine by reaction with a primary amine in the presence of Me ...
URL: http://www.organic-chemistry.org/abstracts/lit1/066.shtm
... in the metathesis reaction. Hydrolysis and Curtius rearrangement then led to 5. Thermodynamically-difficult ... rings offer a particular challenge for ring-closing metathesis. William D. Lubell of the ...
URL: http://www.organic-chemistry.org/Highlights/2005/17October.shtm
... diphenylphosphoryl azide and base resulted in a Curtius rearrangement in which the isocyanate was trapped ... the neighbouring hydroxyl group to give an oxazolidinone. Boc protection followed by the use ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn04/tamiflu-zutter.shtm
... azides, 1,2-azido ethers, Curtius Rearrangement ID: J72-Y2005-2770 ... Safe radical azidonation using polystyrene supported diazidoiodate(I) ...
URL: http://www.organic-chemistry.org/abstracts/literature/326.shtm
... later the first azides appear. A Curtius rearrangement was used to impressively construct a ... carbamate and the Boc-protected amine in one pot. Nice work, as the reaction ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn05/oseltamivir-phosphate-shibasaki.shtm
... chloride, displacement with azide and finally Curtius rearrangement and amide formation. Neatly done ... one pot, but the use of azides is perhaps a drawback. Completion of ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn05/tamiflu-hayashi.shtm
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