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Search results for: epoxidation

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... alkene geometry. Pd-mediated coupling then delivered 3. The preparation of 1 began with epoxidation of carvone followed by oxidative cleavage, to give the keto acid 11. ...
URL: http://www.organic-chemistry.org/Highlights/2016/04January.shtm
... Chem. 2015, 80, 3203.) an improved procedure for the iconic epoxidation of geraniol 1 to 2. John R. Falck of UT Southwestern Medical ...
URL: http://www.organic-chemistry.org/Highlights/2016/22February.shtm
... To establish the absolute configuration of 3, the authors took advantage of Sharpless asymmetric epoxidation. To this end, farnesyl acetate 7 was oxidized with SeO 2 to ...
URL: http://www.organic-chemistry.org/Highlights/2017/03April.shtm
... MOLECULAR-SIEVE CATALYSTS; TANTALUM HYDRIDE COMPLEX; X-RAY-ABSORPTION; MESOPOROUS SILICA; HETEROGENEOUS CATALYSTS; EPOXIDATION CATALYSTS; HYDROCARBON OXIDATION; AERIAL OXIDATION; ADIPIC ACID Molecular sieve catalysts for ...
URL: http://www.organic-chemistry.org/abstracts/authors/thomas-j-m.shtm
... bromide, setting, after hydrolysis, the new secondary stereocenter of 9. Hydroxyl-directed epoxidation gave 10, which was rearranged with Ti(O-i-Pr) 4 to 11 ...
URL: http://www.organic-chemistry.org/Highlights/2005/02May.shtm
... , doing a rather tasty Favorskii rearrrangement on the cyclohexanone (built itself from an epoxidation on carvone, and then opening with chloride). This also generated a ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn03/thapsigargin-ley.shtm
... Design of Sulfides with a Locked Conformation as Promoters of Catalytic and Asymmetric Sulfonium Ylide Epoxidation Marion Davoust, Jean-François Brière, Paul-Alain Jaffrès and Patrick Metzner* *Laboratoire ...
URL: http://www.organic-chemistry.org/abstracts/literature/883.shtm
... tax the group at all; first up was installation of the tertiary alcohol by epoxidation of the silyl enol ether. Desilylation gave them the desired hydroxyl group and ...
URL: http://www.organic-chemistry.org/totalsynthesis/totsyn05/be-43472b-nicolaou.shtm
... achieved. Epoxy alkynes such as 1 can be prepared in high ee by Sharpless epoxidation. Norbert Krause of Dortmund University has shown (Angew. Chem. Int ...
URL: http://www.organic-chemistry.org/Highlights/2007/19November.shtm
... , 17. Key Words: SILYL ENOL ETHERS/OXIDATION-REDUCTION HYDRATION/COMPLEX CATALYZED EPOXIDATION/BAEYER-VILLIGER OXIDATION/SCHIFF-BASE COMPLEXES/ALPHA-HYDROXY KETONES/MOLECULAR-OXYGEN/ASYMMETRIC EPOXIDATION ...
URL: http://www.organic-chemistry.org/abstracts/authors/mukaiyama-t.shtm
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