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... ). CONGRATULATIONS TO RICHARD F. HECK, 2006 H.C. BROWN AWARDEE D ... arylation of indoles. By modulating the reaction conditions, arylation can be directed either ...
... . The vision was that an intramolecular Heck cyclization could then deliver the cripowellin skeleton ... could be used directly in the metathesis reaction. Hydrolysis and Curtius rearrangement then led ...
... . The reaction is probably proceeding via Heck coupling of the aryl halide with the ... led to the ketone 22. The reaction is probably proceeding via Heck coupling of ...
... with 14 is complementary to the long-known Heck coupling of an aryl halide such as ... of an alkyne partner in a trimerization reaction, as illustrated by the regioselective cycloaromatization ...
... iodinated to give 30. A selective Heck reaction on 30 gave 32, that ... carried on to Louisianin C (33). D. F. Taber, ...
