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Search results for: hydroboration

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... 5 set, after oxidation, the three new stereogenic centers of 7. Ir-catalyzed hydroboration led to the primary alcohol, that was carried through aldehyde deprotection and oxidation ...
URL: http://www.organic-chemistry.org/Highlights/2015/01June.shtm
... the equatorial diastereomer 8. This was carried on to the methyl ketone 9. Hydroboration of 9 showed substantial axial preference, to deliver, after oxidation, the ...
URL: http://www.organic-chemistry.org/Highlights/2015/02November.shtm
... trapping with formaldehyde and protection, the ketone 6. Reduction and protection followed by hydroboration led to 7, that was, after protection and deprotection, oxidized to ...
URL: http://www.organic-chemistry.org/Highlights/2015/05October.shtm
... to avoid the undesired equilibration of the pendant group. Regioselectivity and diastereoselectivity in the hydroboration of the alkene 11 was optimized with the enantiomerically-pure borane. Allylation of the ...
URL: http://www.organic-chemistry.org/Highlights/2015/06July.shtm
... University (Org. Lett. 2014, 16, 6452.) effected enantioselective hydroboration of ?-alkyl styrenes, as illustrated by the conversion of 1 to 2. ...
URL: http://www.organic-chemistry.org/Highlights/2015/20July.shtm
... , 20, 13918.) a Co catalyst to effect the room temperature equilibrating hydroboration of an internal alkene 27 to the terminal boronate 28. Maddi Sridar Reddy ...
URL: http://www.organic-chemistry.org/Highlights/2015/25May.shtm
... regioselectivity in the rearrangement of the internal epoxide 5 to the ketone 6. The hydroboration of alkenes is well known. In a variation, Tomoya Miura and Masahiro ...
URL: http://www.organic-chemistry.org/Highlights/2016/12September.shtm
... . 2016, 138, 4338.) the reduction of 20 followed by asymmetric hydroboration to give 21. The C-H insertion process that converted 22 to 23, ...
URL: http://www.organic-chemistry.org/Highlights/2016/24October.shtm
... . Commun. 2016, 52, 5916.) a procedure for the Markovnikov hydroboration of 3 to 4. Donald A. Watson of the University of Delaware ...
URL: http://www.organic-chemistry.org/Highlights/2016/28November.shtm
... . Ed. 2016, 55, 776,) conditions for regioselective and enantioselective hydroboration, converting 1 to 2. The corresponding amines could also be prepared. ...
URL: http://www.organic-chemistry.org/Highlights/2017/13February.shtm
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