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Complex Cyclic Ethers: (+)-Conocarpan (Hashimoto), (-)-Brevisamide (Satake/Tachibana), (+)-Bruguierol A (Fañanás/Rodríguez), (-)-Berkelic Acid (Snider), and (-)-Aigialomycin D (Harvey)
... Wellington illustrated the power of the Ramberg-Bäcklund reaction for the closure of medium rings. ... of Wellington illustrated the power of the Ramberg-Bäcklund reaction for the closure of medium rings ...
... , aqueous formaldehyde works efficiently in the reaction. The telescoping of several synthetic steps ... sulfonates work well also. Note that Ramberg-Bäcklund contraction of the sulfone 17 would give ...