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Synthesis of vinyl trifluoroborates

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The palladium-catalyzed cross-coupling reaction of potassium alkenyltrifluoroborates with aryl and heteroaryl halides and triflates proceeds readily with moderate to excellent yields.
G. A. Molander, C. R. Bernardi, J. Org. Chem., 2002, 67, 8424-8429.

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1-Trifluoroboratoalkenes are oxidized by dioxirane, providing air-stable, crystalline oxiranyltrifluoroborates without cleavage of the carbon-boron bond. The first Suzuki-Miyaura coupling of an epoxytrifluoroborate has been accomplished.
G. A. Molander, M. Ribagorda, J. Am. Chem. Soc., 2003, 125, 11148-11149.