Categories: C-C Bond Formation > Arenes >
Formylation, synthesis of benzaldehydes
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Name Reactions
Recent Literature
O-Aryl N-isopropylcarbamates, conveniently prepared from
phenols and isopropyl isocyanate, are subjected to an efficient ortho-lithiation
protocol to afford the corresponding salicylaldehydes in a one-pot operation
in high yields.
M. Kauch, D. Hoppe,
Synthesis, 2006, 1575-1577.
Reaction of nitroarenes with tris(benzotriazol-1-yl)methyl anion followed by
treatment with zinc bromide and hydrochloric acid yielded the corresponding p-nitroarylaldehydes in good to excellent yields.
A. R. Katritzky, L. Xie, Tetrahedron Lett., 1996,
37, 347-350.
