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Synthesis of 1,2-diols

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A nickel(0) N-heterocyclic carbene complex-catalyzed coupling of α-silyloxy aldehydes and alkynylsilanes provides an effective entry to various anti-1,2-diols with excellent diastereoselectivity.
K. Sa-ei, J. Montgomery, Org. Lett., 2006, 8, 4441-4443.