Categories: C-C Bond Formation > Oxygen-containing molecules > α,β-unsaturated compounds >
Synthesis of enones
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Recent Literature
Aromatic α,β-unsaturated ketones are synthesized efficiently by
palladium-catalyzed cross-coupling reaction of arylboronic acids with
α,β-unsaturated acyl chlorides in the presence of K3PO4
hydrate in toluene.
Y. Urawa, K. Nishiura, S. Souda, K. Ogura, Synthesis, 2003,
2882-2885.
A new method for the synthesis of organoborates starting from α,β-unsaturated
acetals was developed. The available alkoxy-functionalized butadienyl- and
styrylboronic esters cross couple effectively with a broad spectrum of aryl
halides under mild conditions. This method provides an effective
approach to aromatic ketones.
P. B. Tivola, A. Deagostino, C. Prandi, P. Venturello, Org. Lett.,
2002, 4, 1275-1277.
A regioselective intermolecular hydroacylation of vinalarenes, in which
symmetric and mixed carboxylic anhydrides are used as acyl donors, is
promoted by a cationic rhodium catalyst ligated by triphenylarsine.
Y.-T. Hong, A. Barchuk, M. J. Krische, Angew. Chem. Int. Ed., 2006,
45, 6885-6888.
A regioselective intermolecular hydroacylation of vinalarenes, in which
symmetric and mixed carboxylic anhydrides are used as acyl donors, is
promoted by a cationic rhodium catalyst ligated by triphenylarsine.
Y.-T. Hong, A. Barchuk, M. J. Krische, Angew. Chem. Int. Ed., 2006,
45, 6885-6888.
