Categories: C-C Bond Formation > Heteroatom-containing Molecules, Arenes

Synthesis of trifluoromethyl arenes

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A copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with Togni’s reagent proceeded in good to excellent yields for a range of different substrates including heteroarylboronic acids and substrates with a variety of functional groups under mild reaction conditions.
T. Liu, Q. Shen, Org. Lett., 2011, 13, 2342-2345.