Categories: C-C Bond Formation >
Nitrogen-containing molecules
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| Amines |  |
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1,2-Diamines |
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| Hydrazine Derivatives |
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| 1,2-Amino Alcohols |
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1,3-Amino Alcohols |
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| Amino Ketones |
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| α-Amino Acids and Derivatives |
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| β-Amino Acids and Derivatives |
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| Imines |  |
Enamines |  |
Diazo Compounds |  |
| Oximes |  |
Amidines |  |
Hydrazones |  |
| Nitriles |  |
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| Cyanohydrins |
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Aroyl cyanides Alkanoyl cyanides |
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| Aminonitriles |
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| Nitro compounds |
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Recent Literature
Potassium trifluoro(organo)borates, which are highly stable and easily
prepared organoboron derivatives, were able to react with various
dehydroamino esters to alanine derivatives in good to high yields. This
reaction, catalyzed by rhodium complexes, tolerates a great variety of amino
protecting groups.
L. Navarre, S. Darses, J.-P. Genet, Eur. J. Org. Chem., 2004,
69-73.
β-Functionalized sulfonamides were produced in good yields by the
regioselective ring opening of N-tosylaziridines with
trimethylsilylated nucleophiles, catalyzed by N,N,N',N'-tetramethylethylenediamine
(TMEDA).
S. Minakata, Y. Okada, Y. Oderaotoshi, M. Komatsu, Org. Lett.,
2005,
7, 3509-3512.