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Synthesis of 1,2-amino alcohols

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A highly efficient, mild and practical approach for the synthesis of optically pure β-amino alcohols by the SmI2-induced reductive cross-coupling of various chiral N-tert-butanesulfinyl imines with aldehydes was developed.
Y.-W. Zhong, Y.-Z. Dong, K. Fang, K. Izumi, M.-H. Xu, G.-Q. Lin, J. Am. Chem. Soc., 2005, 127, 11956-11957.